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Some comments on the periodic system of elements. International Journal of Quantum Chemistry. SympOSium 3:331-334. Mayer, A. M. 1878. A note on experiments with floating magnets. Alllerican Journal of Sciellce 15:276-277. Mazurs, E. 1974. Gmphic Representatiolls of the Periodic System Durillg One Hundred Years. Tuscaloosa, Alabama: Alabama University Press. , and E. R. Scerri. 1996. Why the 4s orbital is occupied before the 3d. Joumal of ChemiCilI Educatioll 73:498-503. Pauli, W. 1925. Uber den zusammenhang des abschlusses der elektrongruppen im atom lnit der komplexstruktur der spektren.
The procedure consists in solving the time independent Schrodinger for the atom in question. but unfortunately only 29 320 Eric R. Scerri hydrogenic systems such as H. He+ and Li+ 2 which have a single electron posses exact solutions. In the case of many electron atoms. the Hamiltonian operator includes terms due to inter-electronic repulsions. Nobody has yet discovered any means of solving such equations exactly. and a variety of approximation methods have been devised. In the vast majority ofthese schemes it is assumed as a zero order approximation.